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New TEMPO containing polymers for all polymeric oxidation procedure
Journal of Polymer Research ( IF 2.6 ) Pub Date : 2020-01-08 , DOI: 10.1007/s10965-019-1996-x
Perihan Öztürk , Ece Ayça Yücel , Akın Akdag

2,2,6,6-Tetramethylpiperidine 1-oxyl (TEMPO) is a versatile compound which is used mainly in organic oxidation reactions and organic battery applications. Incorporating TEMPO into a polymer could provide many applications into its repertoire. In this study, new polymeric TEMPO derivatives are synthesized and characterized to be used as catalysts in the presence of another polymer which constitutes N-halamine functionality. These polymeric mixtures were superior since the mixture could easily be separated from the reaction medium by simple filtration and reused in some other oxidation reactions numerous times. In turn, an all polymeric oxidation method was developed for oxidation of primary alcohols.



中文翻译:

适用于所有聚合氧化过程的新型含TEMPO聚合物

2,2,6,6-四甲基哌啶1-氧基(TEMPO)是一种通用化合物,主要用于有机氧化反应和有机电池应用中。将TEMPO掺入聚合物中可以为聚合物提供许多应用。在这项研究中,合成了新的聚合物TEMPO衍生物,并表征为在构成N-卤胺官能团的另一种聚合物存在下用作催化剂。这些聚合物混合物是优越的,因为可以通过简单的过滤将混合物容易地从反应介质中分离出来,并在其他一些氧化反应中重复使用多次。继而,开发了用于氧化伯醇的全聚合氧化方法。

更新日期:2020-01-08
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