英国皇家化学会(RSC)是一个超过175年历史的面向全球化学家的非营利会员制机构,旗下拥有44种期刊,其中很多在化学领域有很高影响力。为了进一步帮助广大读者追踪科技前沿热点,X-MOL团队与英国皇家化学会合作,推出英国皇家化学会期刊主编推荐的精彩文章快览,本期文章属“能源领域”,英文点评来自英国皇家化学会期刊的主编。如果大家对我们的解读有更多的补充和点评,欢迎在文末写评论发表您的高见!
Chemical Science (IF: 9.063)
1. Facet-dependent photocatalytic hydrogen production of metal–organic framework NH2-MIL-125(Ti)
Chem. Sci., 2019, Advance Article
DOI: 10.1039/C8SC05060K
Scientists at Nanjing University investigated the surface structure of a NH2-MIL-125(Ti) MOF using DFT for the first time. They find that the {110} facet has the best surface energy, as a result of it having more exposed metal clusters, which are able to act as active sites in catalysis. They then use this MOF in the photocatalytic production of hydrogen and show that the sample containing the {110} facet exhibits the best performance.
南京大学的科学家首次使用密度泛函理论(DFT)研究了NH2-MIL-125(Ti) MOF材料的表面结构。他们发现{110}面具有更多能够在催化中作为活性位点的暴露金属簇,因而具有最佳的表面能。然后他们将该MOF用于光催化产氢,发现含有{110}面的样品表现出了最佳的性能。
Open Access(可免费阅读原文)
扫描或长按二维码,识别后直达原文页面,或点此查看原文
2. Reversible perovskite electrocatalysts for oxygen reduction/oxygen evolution
Chem. Sci., 2018, Advance Article
DOI: 10.1039/C9SC00412B
Researchers from the University of Southampton (UK) have highlighted a general strategy to optimise oxide electrocatalysts for the ORR and OER. They say that currently there is an open question around whether a bifunctional catalyst or a single catalyst site will exhibit potential converging to +1.23 V. In this work the authors use LaxMnyNi1−yO3−δ, based perovskites and investigate the role of A and B-site substitution.
英国南安普顿大学的研究人员重点介绍了一种优化用于氧还原反应(ORR)和析氧反应(OER)的氧化物电催化剂的通用策略。他们提出目前存在的一个悬而未决的问题是双功能催化剂或单一催化剂位点是否能表现出+1.23 V左右的电位。在本研究中,作者们使用了一种基于LaxMnyNi1−yO3−δ 的钙钛矿研究了镧A位点和B位点取代的作用。
Open Access(可免费阅读原文)
扫描或长按二维码,识别后直达原文页面,或点此查看原文
Sustainable Energy & Fuels (IF pending)
1. Energetic effects of hybrid organic/inorganic interfacial architecture on nanoporous black silicon photoelectrodes
Sustainable Energy Fuels, 2019, Advance Article
DOI: 10.1039/C9SE00032A
This work demonstrates the sensitive nature of the thermodynamics and kinetics on the interfacial architecture and yields critical insights into the design of photoelectrochemical interfaces.
这项工作证明了界面结构热力学和动力学的敏感性,并为光电化学界面的设计提供了重要见解。
限时免费阅读原文,登陆后可下载
扫描或长按二维码,识别后直达原文页面,或点此查看原文
2. Sonochemical deposition of ultrafine metallic Pt nanoparticles on CdS for efficient photocatalytic hydrogen evolution
Sustainable Energy Fuels, 2019, Advance Article
DOI: 10.1039/C9SE00050J
This work offers a simple but effective approach to the deposition of noble metal Pt as an efficient cocatalyst on CdS for high photocatalytic H2 evolution.
本文介绍了一种简单但有效的方法,可以在CdS上沉积贵金属铂作为有效的助催化剂,用于高效光催化产氢。
限时免费阅读原文,登陆后可下载
扫描或长按二维码,识别后直达原文页面,或点此查看原文
Energy & Environmental Science (IF: 30.067)
1. Energy landscape of the charge transfer reaction at the complex Li/SEI/electrolyte interface
Energy Environ. Sci., 2019, Advance Article
DOI: 10.1039/C8EE03586E
The charge transfer reaction is the fundamental reaction for rechargeable batteries. In this paper, a new modeling framework was developed to predict the energy landscape of the lithiation/delithiation charge transfer reaction.
电荷转移反应是可充电电池的基本反应。在本文中,作者开发了一种新的模型框架来预测锂化/脱锂电荷转移反应的能量全景图。
限时免费阅读原文,登陆后可下载
扫描或长按二维码,识别后直达原文页面,或点此查看原文
2. A general route via formamidecondensation to prepare atomically dispersed metal–nitrogen–carbon electrocatalysts for energy technologies
Energy Environ. Sci., 2019, Advance Article
DOI: 10.1039/C9EE00162J
This work offers a feasible approach to design and manufacture SAECs with tuneable atomic metal components and high density of single-site metal loading, and thus may accelerate the deployment of SAECs for various energy technology applications.
本文提供了一种可行的方法来设计和制造具有可调的原子金属组分和高密度的单位点金属负载的单原子电催化剂(SAEC),由此或可加速SAEC在多种能源技术中的应用。
限时免费阅读原文,登陆后可下载
扫描或长按二维码,识别后直达原文页面,或点此查看原文
如果篇首注明了授权来源,任何转载需获得来源方的许可!如果篇首未特别注明出处,本文版权属于 X-MOL ( x-mol.com ), 未经许可,谢绝转载!