RSC主编推荐：有机化学领域精彩文章快览（免费阅读原文）

英国皇家化学会（RSC）是一个拥有175年历史的面向全球化学家的非营利会员制机构，旗下拥有43种期刊，其中很多在化学领域有很高影响力。为了进一步帮助广大读者追踪科技前沿热点，X-MOL团队与英国皇家化学会合作，推出英国皇家化学会期刊主编推荐的精彩文章快览，本期文章属“有机化学领域”，英文点评来自英国皇家化学会期刊的主编。如果大家对我们的解读有更多的补充和点评，欢迎在文末写评论发表您的高见！

Organic Chemistry Frontiers (IF: 4.693)

1. A chiral ion-pair photoredox organocatalyst: enantioselective anti-Markovnikov hydroetherification of alkenols

Org. Chem. Front., 2017, Advance Article

DOI: 10.1039/C6QO00806B

A chiral ion-pair photoredox organocatalyst was reported to facilitate visible-light-meditated asymmetric anti-Markovnikov hydroetherification of alkenols with high reactivity and moderate enantioselectivity.

本文报道了利用一种手性离子对光氧化还原有机分子催化剂促进可见光参与的不对称反马氏烯醇氢化成醚反应，该反应具有较高的反应活性和中等的对映选择性。

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2. A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

Org. Chem. Front., 2017, Advance Article

DOI: 10.1039/C7QO00111H

An effective palladium-catalyzed sequential carbonylation of olefins with formic acid is described. Ketones and the corresponding α,β-enones can be obtained with up to 90% yield. The reaction process is operationally simple and requires no toxic CO.

本文报道了一种钯催化的烯烃与甲酸的高效连续羰基化反应，该反应可以以高达90%的收率制备酮和相应的α,β-烯酮，且操作简单，无需使用有毒的一氧化碳。

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3. KBr/K₂S₂O₈-mediated dibromohydration of N-(2-alkynylaryl)acetamide

Org. Chem. Front., 2017, Advance Article

DOI: 10.1039/C6QO00840B

A neighbouring group-participated metal-free dibromohydration of internal alkyne was reported by Qiu, G. and Zhou, H. et al. By employing different neighbouring groups, switchable synthesis could be achieved. The entire process of dibromohydration went under mild conditions with high regioselectivity. An insight into the reaction mechanism suggested that water served as a nucleophile to be incorporated into the acetamino group.

嘉兴学院周宏伟课题组报道了一种邻位基团参与的分子内炔烃双溴水合反应，该反应不需要使用金属催化剂，通过引入不同的邻位基团可以合成不同的产物。该双溴化水合反应条件温和，具有很好的区域选择性。考察反应机理发现，反应过程中水分子作为亲核试剂可以与酰胺基团反应。

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Chemical Science (IF: 9.144)

1. Divergent enantioselective synthesis of hapalindole-type alkaloids using catalytic asymmetric hydrogenation of a ketone to construct the chiral core structure

Chem. Sci., 2016, 7, 4725-4729

DOI: 10.1039/C6SC00686H

Nankai University researchers report an elegant and creative approach to the synthesis of hapalindoles, which are attracting interest as alkaloid synthetic targets due to their unique and diverse molecular architectures and broad range of biological activities.

南开大学的研究人员报道了一种简单新颖的方法合成hapalindoles，该类生物碱由于独特多样的分子结构和广谱的生物活性正受到越来越多的关注。

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