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UV absorption spectra of trans-2-pentenal, trans-2-hexenal and 2-methyl-2-pentenal
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2019-01-23 , DOI: 10.1016/j.cplett.2019.01.028
C. Kalalian , B. Samir , E. Roth , A. Chakir

C5 and C6 unsaturated aldehydes are a category of BVOCs released by plants in response to their wounds and stress. In this work, the gas phase UV absorption spectra of trans-2-pentenal (t-2P), trans-2-hexenal (t-2H) and 2-methyl-2-pentenal (2M2P) are determined between 240 and 400 nm, at room temperature and at pressures (1-9) torr. The reported UV absorption cross sections are (cm2molecule-1): σt-2P, 330 = (4.86 ± 0.53) x 10-20, σt-2H, 330 = (5.43 ± 0.57) x 10-20 and σ2M2P, 320 = (6.62 ± 0.50) x 10-20. Their photolysis constants as well as their atmospheric lifetimes toward photolysis were then estimated.



中文翻译:

反式-2-戊烯醛,反式-2-己醛和2-甲基-2-戊烯醛的紫外吸收光谱

C 5和C 6不饱和醛是植物响应伤口和胁迫而释放的BVOC的一​​类。在这项工作中,测定了在240至400 nm之间的反式2-戊烯醛(t-2P),反式-2-己烯醛(t-2H)和2-甲基-2-戊烯醛(2M2P)的气相UV吸收光谱,在室温和压力(1-9)托下。报告的UV吸收截面为(cm 2分子-1):σt -2P,330 =(4.86±0.53)x 10 -20,σt -2H,330 =(5.43±0.57)x 10 -20和σ 2M2P,320 =(6.62±0.50)x 10 -20。然后估算了它们的光解常数以及大气中光解的寿命。

更新日期:2019-01-24
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