Abstract The invention of bulk metallic glasses has stimulated extensive interest, due to their possible technological applications in a variety of industrial fields and their scientific importance in understanding related condensed matter physics. Among all types of BMGs, Fe-based BMGs are a unique yet important family due to their high mechanical strength, good thermal stability, strong corrosion resistance, excellent soft magnetic properties, and relatively low production costs. Since the first synthesis of the Fe-Al-Ga-P-C-B BMG reported in 1995, a vast body of literature regarding Fe-based BMGs has been published. However, until now, a full and systematic description of the development status and future prospects of Fe-based BMGs has been missing. Therefore, this article presents the research development and achievements of Fe-based BMGs in the past few decades, including their preparation, glass-forming ability, crystallization characteristics, mechanical properties, corrosion behaviors, soft and hard magnetic properties, and industrial applications. In addition, future developments of Fe-based BMGs are also proposed.

中文翻译：

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铁基块状金属玻璃：玻璃的形成、制造、性能和应用

摘要 块状金属玻璃的发明引起了广泛的兴趣，因为它们可能在各种工业领域中应用技术，并且在理解相关凝聚态物理方面具有重要的科学意义。在所有类型的 BMGs 中，Fe 基 BMGs 因其机械强度高、热稳定性好、耐腐蚀性强、软磁性能优异以及相对较低的生产成本而成为一个独特而重要的家族。自 1995 年首次合成 Fe-Al-Ga-PCB BMG 以来，已经发表了大量关于 Fe 基 BMG 的文献。然而，到目前为止，还缺乏对铁基BMGs的发展现状和未来前景的全面系统的描述。所以，本文介绍了Fe基BMGs在过去几十年的研究进展和成果，包括其制备、玻璃形成能力、结晶特性、力学性能、腐蚀行为、软硬磁性能和工业应用。此外，还提出了铁基 BMGs 的未来发展。