Direct synthesis of aromatics from syngas is a split-new research direction of coal-to-chemicals industry over the years. The effects of Zn and K on FeZr catalysts combined with Ni modified zeolite (Ni/HZSM-5) were investigated for the reaction. Modified catalysts exhibited excellent catalytic activity, showing superior selectivity of aromatic products (more than 82% in C₅₊ hydrocarbons) under stable CO conversion over 90%. The results demonstrated that catalyst structure could be adjusted by controlling Zn content and the acidic properties could be regulated by introducing K as a promoter. Finally, the total aromatic selectivity was conclusively ascended to 39.48%, with a controlled selectivity of CO₂ lower than 25%.

从合成气直接合成芳烃是多年来煤化工行业的一个新的研究方向。研究了Zn和K对FeZr催化剂和Ni改性沸石（Ni / HZSM-5）结合反应的影响。改性的催化剂表现出优异的催化活性，在稳定的CO转化率超过90％时，芳烃产物（在C ₅₊烃中大于82％）表现出优异的选择性。结果表明，通过控制锌含量可以调节催化剂的结构，而引入钾作为助催化剂可以调节其酸性。最后，总芳烃选择性最终提高到39.48％，而CO ₂的受控选择性低于25％。