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Reduction of phosphine oxides to phosphines
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-12-30 , DOI: 10.1016/j.tetlet.2018.12.070
Evgeniya Podyacheva , Ekaterina Kuchuk , Denis Chusov

The digest is devoted to the most widespread reducing agents which are used for the reduction of tertiary and secondary phosphine oxides, phospholene oxides, phospholane oxides, phosphonates, phosphinates, α- and β-hydroxy and thiomethyl phosphine oxides, α-aminophosphine oxides. Stereoselectivity of reactions is described. Methods of stabilization of phosphines which are prone to re-oxidation by the formation of borane-adduct or metal complexes are considered.



中文翻译:

将氧化膦还原为膦

该消化物专门用于最广泛的还原剂,该还原剂用于还原叔膦氧化物和仲膦氧化物,磷烯氧化物,磷戊烯氧化物,膦酸酯,次膦酸酯,α-和β-羟基和硫代甲基膦氧化物,α-氨基膦氧化物。描述了反应的立体选择性。考虑了通过形成硼烷加合物或金属络合物而易于再氧化的膦的稳定化方法。

更新日期:2018-12-30
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