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Hydride Transfer Reactions Catalyzed by Cobalt Complexes
Chemical Reviews ( IF 51.4 ) Pub Date : 2018-12-19 00:00:00 , DOI: 10.1021/acs.chemrev.8b00404 Wenying Ai 1 , Rui Zhong 1 , Xufang Liu 1 , Qiang Liu 1
Chemical Reviews ( IF 51.4 ) Pub Date : 2018-12-19 00:00:00 , DOI: 10.1021/acs.chemrev.8b00404 Wenying Ai 1 , Rui Zhong 1 , Xufang Liu 1 , Qiang Liu 1
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Cobalt has become increasingly attractive in homogeneous catalysis because of its unique characteristics and outstanding catalytic performance in addition to being cheap and earth-abundant. Hydride transfer processes are involved in a broad range of organic transformations that allow the facile preparation of various useful chemicals and synthetic building blocks. These reactions have continuously received great attention both from academia and industry. In this perspective, we review homogeneous cobalt-catalyzed hydride transfer reactions according to the classified reaction types and provide a comprehensive overview of the design, synthesis, and reactivity of cobalt catalysts, their catalytic applications, and reaction mechanisms.
中文翻译：
钴配合物催化的氢化物转移反应
钴由于其独特的特性和卓越的催化性能，不仅价格便宜且富含地球，因此在均相催化中已变得越来越有吸引力。氢化物转移过程涉及广泛的有机转化，可轻松制备各种有用的化学物质和合成构件。这些反应一直受到学术界和工业界的高度重视。从这个角度出发，我们根据分类的反应类型回顾了均相钴催化的氢化物转移反应，并对钴催化剂的设计，合成和反应性，其催化应用和反应机理进行了全面概述。
更新日期：2018-12-19
中文翻译：
钴配合物催化的氢化物转移反应
钴由于其独特的特性和卓越的催化性能，不仅价格便宜且富含地球，因此在均相催化中已变得越来越有吸引力。氢化物转移过程涉及广泛的有机转化，可轻松制备各种有用的化学物质和合成构件。这些反应一直受到学术界和工业界的高度重视。从这个角度出发，我们根据分类的反应类型回顾了均相钴催化的氢化物转移反应，并对钴催化剂的设计，合成和反应性，其催化应用和反应机理进行了全面概述。
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