Catalysis Communications ( IF 3.4 ) Pub Date : 2018-12-18 , DOI: 10.1016/j.catcom.2018.12.008 Baiyu Jiang , Feng He , Pengjia Yang , Zhen Zhang , Yuhong Weng , Zhenmei Cheng , Zhisheng Fu , Zhiqiang Fan
Propylene polymerization with two TiCl4/MgCl2 catalysts (Cat-1: Ti 0.1%; Cat-2: Ti 1.0%) showed different responses to (cyclo-C5H9)2Si(OCH3)2 (De) addition. Cat-1 was deactivated more than Cat-2 by De. Amount of three groups of active centers producing atactic, medium isotactic and isotactic polypropylene chains were all reduced by De addition, but those of Cat-1 were reduced more. Reactivity of the isospecific active centers (kpi) was enhanced by De, but kpi of Cat-2 was changed more sensitively than Cat-1. The lower stereoselectivity of Cat-1 than Cat-2 are attributable to weaker De adsorption on its surface Mg, and the more sparsely dispersed Ti species on Cat-1 is responsible for weak De adsorption.
中文翻译:
电子给体增强MgCl 2负载的齐格勒-纳塔催化剂对丙烯聚合的立体选择性:钛分散态的强效应
用两种TiCl 4 / MgCl 2催化剂(Cat-1:Ti 0.1%; Cat-2:Ti 1.0%)进行的丙烯聚合显示出对(环C 5 H 9)2 Si(OCH 3)2(De)添加的不同响应。De对Cat-1的作用比对Cat-2的作用更大。通过添加De减少了产生无规,中等规和等规聚丙烯链的三组活性中心的数量,但是Cat-1的活性中心被进一步还原。De提高了同种异性活性中心的反应性(k pi),但k piCat-2的变化比Cat-1更敏感。Cat-1的立体选择性比Cat-2低,这归因于其表面Mg上的De吸附较弱,而Cat-1上Ti的分布较稀疏是De吸附较弱的原因。