High iso Aldehyde Selectivity in the Hydroformylation of Short‐Chain Alkenes,Angewandte Chemie International Edition

当前位置： X-MOL 学术 › Angew. Chem. Int. Ed. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

High iso Aldehyde Selectivity in the Hydroformylation of Short‐Chain Alkenes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2019-01-18 , DOI: 10.1002/anie.201811888
Leo Iu ₁ , José A. Fuentes ₁ , Mesfin E. Janka ₂ , Kevin J. Fontenot ₂ , Matthew L. Clarke ₁

Affiliation

The hydroformylation of propene to give predominantly iso‐butanal has been achieved; class‐leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos‐biphenols and unusual solvent systems are the key to the selectivity observed.

中文翻译：