Annulating thiazolium cations via a direct double C–H activation strategy: Rh–N,S-heterocyclic carbene is the key†,Chemical Communications

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Annulating thiazolium cations via a direct double C–H activation strategy: Rh–N,S-heterocyclic carbene is the key†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-12-14 00:00:00 , DOI: 10.1039/c8cc07531j
Champak Dutta _{1,

2,

3,

4,

5} , Arppitha Baby Sainaba _{1,

2,

3,

4,

5} , Joyanta Choudhury _{1,

2,

3,

4,

5}

Affiliation

Herein we show how metal–N,S-heterocyclic carbene intermediates are conveniently generated and utilized for the first time to construct N,S doubly-doped cationic conjugated tricyclic organic molecules which exhibit tuneable emission. The chemistry proceeds via direct double C–H activation followed by an annulative π-extension pathway.

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