Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(i) migration†,Chemical Communications

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Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(i) migration†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-12-14 00:00:00 , DOI: 10.1039/c8cc09238a
Rebecca E. Ruscoe _{1,

2,

3,

4,

5} , Michael Callingham _{1,

2,

3,

4,

5} , Joshua A. Baker _{1,

2,

3,

4,

5} , Stamatis E. Korkis _{1,

2,

3,

4,

5} , Hon Wai Lam _{1,

2,

3,

4,

5}

Affiliation

A novel multicomponent coupling reaction involving the iridium-catalyzed 1,5-difunctionalization of 1,3-enynes with arylboronic acids and triazinanes is described. A key step in this 1,5-(aryl)aminomethylation reaction is the alkenyl-to-allyl 1,4-iridium(I) migration.

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