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Electroresponsive Polymer–Inorganic Semiconducting Composite (MCTP–Fe3O4) Particles and Their Electrorheology
ACS Omega ( IF 3.7 ) Pub Date : 2018-12-13 00:00:00 , DOI: 10.1021/acsomega.8b02731
Yu Zhen Dong , Seung Hyuk Kwon , Hyoung Jin Choi , Pillaiyar Puthiaraj , Wha-Seung Ahn

Polymer–inorganic semiconducting composite (MCTP–Fe3O4) particles were fabricated by loading nanosized Fe3O4 on the microporous covalent triazine-based polymer (MCTP) through a chemical coprecipitation method and then applied to an electrorheological (ER) material. The structural and morphological images of MCTP–Fe3O4 composite were examined by scanning electron microscopy, transmission electron microscopy, and X-ray diffraction. Their magnetic property was also investigated by vibrating sample magnetometry. The chain structure formation of MCTP–Fe3O4 dispersed in silicone oil under an external electric field was confirmed using an optical microscope. The ER fluid based on MCTP–Fe3O4 was processed by dispersing the composite particles in an oil medium, and for comparison, an ER fluid based on pure MCTP was also prepared by the same process. The ER performance of two different ER fluids was scrutinized by a rotational rheometer, which demonstrated that MCTP–Fe3O4 showed better ER characteristics than MCTP-based ER suspension.

中文翻译:

电响应性聚合物-无机半导体复合材料(MCTP-Fe 3 O 4)颗粒及其流变学

聚合物-无机半导体复合材料(MCTP -铁3 ö 4)颗粒被装载纳米的Fe制成3 Ò 4在微孔基三嗪的共价聚合物(MCTP)通过化学共沉淀法,然后施加到电流变(ER)材料。通过扫描电子显微镜,透射电子显微镜和X射线衍射检查了MCTP-Fe 3 O 4复合材料的结构和形态图像。还通过振动样品磁力分析法研究了它们的磁性。MCTP–Fe 3 O 4的链结构形成使用光学显微镜确认在外部电场下分散在硅油中。通过将复合颗粒分散在油介质中来处理基于MCTP–Fe 3 O 4的ER流体,为进行比较,还通过相同的方法制备了基于纯MCTP的ER流体。通过旋转流变仪仔细检查了两种不同的ER流体的ER性能,这表明MCTP–Fe 3 O 4表现出比基于MCTP的ER悬浮液更好的ER特性。
更新日期:2018-12-13
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