Use of Boron‐Doped Diamond Electrodes in Electro‐Organic Synthesis,ChemElectroChem

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Use of Boron‐Doped Diamond Electrodes in Electro‐Organic Synthesis
ChemElectroChem ( IF 3.5 ) Pub Date : 2019-01-22 , DOI: 10.1002/celc.201801620
Sebastian Lips ₁ , Siegfried R. Waldvogel ₁

Affiliation

Boron‐doped diamond is a powerful and innovative material with outstanding properties, experiencing a strongly emerging interest in the chemical society as electrode material. BDD is generally used as a p‐doped semiconductor that can be applied for the disinfection and detoxification of waste‐water since very reactive intermediates can be formed. Besides this destructive performance of BDD electrodes the extraordinary characteristics can also be successfully employed in electro‐synthetic transformations. The performance is usually beyond and much superior to common electrode materials. A key step for the broad interdisciplinary field of application of this particular electrode material is the direct generation of oxyl radicals by electrochemical oxidation. The intention of this mini‐review is to provide the reader a brief overview of the current state of research and to illustrate the different fields of application. The methods applied are critically reviewed.

中文翻译：

硼掺杂金刚石电极在有机合成中的应用

掺硼金刚石是一种功能强大且创新的材料，具有出色的性能，在化学社会中，电极材料引起了人们的浓厚兴趣。BDD通常用作掺杂的半导体，由于可以形成非常活泼的中间体，因此可用于废水的消毒和解毒。除了BDD电极的这种破坏性性能外，非凡的特性还可以成功地用于电合成转换中。该性能通常超过普通电极材料，并且要远远优于普通电极材料。该特定电极材料在广泛的跨学科应用领域中的关键步骤是通过电化学氧化直接生成羟基自由基。本微型审阅的目的是为读者提供有关当前研究状态的简要概述，并说明不同的应用领域。严格审查了所应用的方法。

更新日期：2019-01-22

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