当前位置: X-MOL 学术Chem. Commun. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Rhodium(iii)-catalyzed aromatic C–H cyanation with dimethylmalononitrile as a cyanating agent†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-12-10 00:00:00 , DOI: 10.1039/c8cc08930b
He Li 1, 2, 3 , Sheng Zhang 1, 2, 3 , Xiaoqiang Yu 1, 2, 3 , Xiujuan Feng 1, 2, 3 , Yoshinori Yamamoto 1, 2, 3, 4, 5 , Ming Bao 1, 2, 3, 6, 7
Affiliation  

A rhodium-catalyzed aromatic C–H bond direct cyanation with safe, bench-stable, and commercially available dimethylmalononitrile as the cyanating agent has been successfully developed by using copper oxide as a promotor. Pyridine, quinoline, pyrimidine and pyrazole were used as the directing group in this type of C–H bond direct cyanation reaction.

中文翻译:

铑(iii)催化的芳族CH–H氰化,以二甲基丙二腈为氰化剂

通过使用氧化铜作为促进剂,成功开发出了铑催化的芳香族CH键直接氰化,安全,稳定和可商购的二甲基丙二腈作为氰化剂。吡啶,喹啉,嘧啶和吡唑被用作这种C–H键直接氰化反应的导向基团。
更新日期:2018-12-10
down
wechat
bug