Visible-light mediated carbamoyl radical addition to heteroarenes†,Chemical Communications

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Visible-light mediated carbamoyl radical addition to heteroarenes†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-12-06 00:00:00 , DOI: 10.1039/c8cc08326f
Ashique Hussain Jatoi _{1,

2,

3,

4,

5} , Govind Goroba Pawar _{1,

2,

3,

4,

5} , Frédéric Robert _{1,

2,

3,

4,

5} , Yannick Landais _{1,

2,

3,

4,

5}

Affiliation

The generation of carbamoyl radicals, followed by their addition to heteroarenes, was performed under mild conditions through a metal-free photocatalyzed decarboxylation of oxamic acids. The process has been applied to the carbamoylation of heteroaromatic bases using α-aminoacid-derived oxamic acids, leading to the corresponding amides without racemization.

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