当前位置: X-MOL 学术Catal. Today › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Immobilization of a selective Ru-pincer complex for low temperature methanol reforming–Material and process improvements
Catalysis Today ( IF 5.3 ) Pub Date : 2018-12-05 , DOI: 10.1016/j.cattod.2018.12.005
Christian H. Schwarz , Anastasiya Agapova , Henrik Junge , Marco Haumann

A homogeneous Ru-pincer complex was immobilized by the supported liquid phase (SLP) technique and tested in continuous gas-phase steam reforming of methanol. Variations of catalyst composition (liquid phase, base and catalyst loading) as well as process parameters (temperature, flow rate) were carried out. High activity was obtained when ionic liquids were used for catalyst immobilization. However, better stability was obtained in the absence of ionic liquids using pure KOH.



中文翻译:

为低温甲醇重整而固定的选择性Ru-钳子配合物的固定化-材料和工艺的改进

通过负载型液相(SLP)技术固定了均匀的Ru-钳子配合物,并在甲醇的连续气相蒸汽重整中进行了测试。进行了催化剂组成(液相,碱和催化剂负载量)以及工艺参数(温度,流速)的变化。当将离子液体用于催化剂固定化时,获得了高活性。但是,使用纯KOH在不存在离子液体的情况下可获得更好的稳定性。

更新日期:2019-12-11
down
wechat
bug