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Before Li Ion Batteries
Chemical Reviews ( IF 51.4 ) Pub Date : 2018-11-30 00:00:00 , DOI: 10.1021/acs.chemrev.8b00422 Martin Winter 1 , Brian Barnett 2 , Kang Xu 3
Chemical Reviews ( IF 51.4 ) Pub Date : 2018-11-30 00:00:00 , DOI: 10.1021/acs.chemrev.8b00422 Martin Winter 1 , Brian Barnett 2 , Kang Xu 3
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This Review covers a sequence of key discoveries and technical achievements that eventually led to the birth of the lithium-ion battery. In doing so, it not only sheds light on the history with the advantage of contemporary hindsight but also provides insight and inspiration to aid in the ongoing quest for better batteries of the future. A detailed retrospective on ingenious designs, accidental discoveries, intentional breakthroughs, and deceiving misconceptions is given: from the discovery of the element lithium to its electrochemical synthesis; from intercalation host material development to the concept of dual-intercalation electrodes; and from the misunderstanding of intercalation behavior into graphite to the comprehension of interphases. The onerous demands of bringing all critical components (anode, cathode, electrolyte, solid-electrolyte interphases), each of which possess unique chemistries, into a sophisticated electrochemical device reveal that the challenge of interfacing these originally incongruent components often outweighs the individual merits and limits in their own properties. These important lessons are likely to remain true for the more aggressive battery chemistries of future generations, ranging from a revisited Li-metal anode, to conversion-reaction type chemistries such as Li/sulfur, Li/oxygen, and metal fluorides, and to bivalent cation intercalations.
中文翻译：
锂离子电池使用之前
这篇综述涵盖了一系列关键发现和技术成就，这些最终发现和技术成就最终导致了锂离子电池的诞生。这样一来，它不仅可以利用当代的后见之明来阐明历史，而且可以提供洞察力和灵感，以帮助人们不断寻求更好的未来电池。详细介绍了巧妙的设计，意外发现，有意突破和欺骗性误解。从插层主体材料的发展到双插层电极的概念；从对石墨插层行为的误解到对相的理解。带来所有关键组件（阳极，阴极，电解质，固体电解质中间相）（每种具有独特的化学性质）到复杂的电化学装置中，表明将这些最初不相容的组分连接起来所面临的挑战通常超过了各自的优点和自身性能的局限性。这些重要的教训对于下一代更积极的电池化学方法可能仍然适用，范围从重新审视的锂金属阳极到转化反应型化学方法（例如锂/硫，锂/氧和金属氟化物）以及二价阳离子插层。
更新日期：2018-11-30
中文翻译：
锂离子电池使用之前
这篇综述涵盖了一系列关键发现和技术成就，这些最终发现和技术成就最终导致了锂离子电池的诞生。这样一来，它不仅可以利用当代的后见之明来阐明历史，而且可以提供洞察力和灵感，以帮助人们不断寻求更好的未来电池。详细介绍了巧妙的设计，意外发现，有意突破和欺骗性误解。从插层主体材料的发展到双插层电极的概念；从对石墨插层行为的误解到对相的理解。带来所有关键组件（阳极，阴极，电解质，固体电解质中间相）（每种具有独特的化学性质）到复杂的电化学装置中，表明将这些最初不相容的组分连接起来所面临的挑战通常超过了各自的优点和自身性能的局限性。这些重要的教训对于下一代更积极的电池化学方法可能仍然适用，范围从重新审视的锂金属阳极到转化反应型化学方法（例如锂/硫，锂/氧和金属氟化物）以及二价阳离子插层。
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