A Green Approach: Vicinal Oxidative Electrochemical Alkene Difunctionalization,ChemElectroChem

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A Green Approach: Vicinal Oxidative Electrochemical Alkene Difunctionalization
ChemElectroChem ( IF 3.5 ) Pub Date : 2018-12-10 , DOI: 10.1002/celc.201801466
Guilherme M. Martins _{1,

2} , Bahareh Shirinfar ₃ , Tomas Hardwick ₄ , Nisar Ahmed _{1,

3}

Affiliation

Electrochemistry is now regarded as one of the most efficient ways to synthesize highly functionalized moieties, such as those of the difunctionalized vicinal alkene family, from simpler and more commercially available substrates. These vicinal transformations usually involve transition‐metal catalysts, hypervalent iodine reagents, or photocatalysts to form new bonds and often generate unwanted by‐products. Herein, we have outline examples of electrochemical alkene difunctionalization reactions that do not require a metal catalyst incorporated into the solution and yet still proceed with excellent atom economies.

中文翻译：

绿色方法：邻域氧化电化学烯烃双官能化

如今，电化学被认为是从更简单，更可商购的底物中合成高度官能化部分（例如双官能邻位烯烃家族的部分）的最有效方法之一。这些邻近的转化通常涉及过渡金属催化剂，高价碘试剂或光催化剂，以形成新的键，并经常产生不需要的副产物。在此，我们概述了电化学烯烃双官能化反应的示例，这些反应不需要将金属催化剂掺入溶液中，而且仍具有出色的原子经济性。

更新日期：2018-12-10

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