Novel glass-ceramic electrolytes of (100-x) (70Li₂S-30P₂S₅)-xNi₂P (x = 0, 1, 2, 3, 4) with high ionic conductivity were proposed with the addition of Ni₂P. The 2 mol% Ni₂P containing electrolyte (Li₇Ni_0.2P_3.1S₁₁) displays the highest lithium-ion conductivity of 2.22 mS cm⁻¹ at room temperature, which is 1.6 times higher than pristine Li₇P₃S₁₁. By direct combination with Li₂S, the fabricated Li₇Ni_0.2P_3.1S₁₁-Li₂S all-solid-state battery exhibits an initial discharge capacity of 429 mAh g⁻¹ at 0.064 mA cm⁻² and 454 mAh g⁻¹ at 20th charging/discharging cycle with a high Coulombic efficiency of 99.7%.

（100-X）（70Li的新颖玻璃-陶瓷的电解质₂ S-30P ₂小号₅）-xNi ₂ P（X = 0，1，2，3，4）具有高的离子传导性，提出了用添加Ni ₂ P.含有2 mol％Ni ₂ P的电解质（Li ₇ Ni _0.2 P _3.1 S ₁₁）在室温下显示出最高的锂离子电导率，为2.22 mS cm ^-1，是原始Li ₇ P ₃ S的1.6倍₁₁。通过与Li ₂ S直接结合，制得的Li ₇ Ni _0.2 P_3.1 S ₁₁ -Li ₂ S全固态电池的初始放电容量为0.064 mA cm ^-2时的初始放电容量为429 mAh g ^-1，在第20个充电/放电循环中的初始放电容量为454 mAh g ^-1，库仑效率高达99.7％。 。