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Two-dimensional vanadium carbide (V2C) MXene as electrode for supercapacitors with aqueous electrolytes
Electrochemistry Communications ( IF 4.7 ) Pub Date : 2018-10-16 , DOI: 10.1016/j.elecom.2018.10.012
Qingmin Shan , Xinpeng Mu , Mohamed Alhabeb , Christopher E. Shuck , Di Pang , Xin Zhao , Xue-Feng Chu , Yingjin Wei , Fei Du , Gang Chen , Yury Gogotsi , Yu Gao , Yohan Dall'Agnese

Recently, a large family of 2D materials called MXenes have attracted much attention in the field of supercapacitors, thanks to the excellent performance demonstrated by Ti3C2 MXene-based electrodes. However, research on MXenes for supercapacitor applications has been primarily focused on Ti3C2, even though there are more than 20 other members of this large family of materials already available. Studies on other MXenes are emerging, with promising results already achieved by Ti2C, Mo2C, and Mo1.33C in aqueous electrolytes. Yet, many other MXenes remain unexplored in aqueous supercapacitor applications. In this work, we report on the electrochemical behavior of a vanadium carbide MXene, V2C, in three aqueous electrolytes. Excellent specific capacitances were achieved, specifically 487 F/g in 1 M H2SO4, 225 F/g in 1 M MgSO4, and 184 F/g in 1 M KOH, which are higher than previously reported values for few micrometer-thick delaminated MXene electrodes. This work shows the promise of V2C MXene for energy storage using aqueous electrolytes.



中文翻译:

二维碳化钒(V 2 C)MXene作为带有水性电解质的超级电容器的电极

最近,由于Ti 3 C 2 MXene基电极表现出的出色性能,称为MXene的大量2D材料家族在超级电容器领域引起了很多关注。然而,关于超级电容器应用的MXene的研究主要集中在Ti 3 C 2上,尽管已经有20多种这种大型材料家族的其他成员。有关其他MXene的研究正在兴起,Ti 2 C,Mo 2 C和Mo 1.33已经取得了可喜的结果。C在水性电解质中。然而,许多其他MXene在水性超级电容器应用中仍未开发。在这项工作中,我们报告了碳化钒MXene V 2 C在三种水性电解质中的电化学行为。实现了出色的比电容,特别是在1 MH 2 SO 4中为487 F / g,在1 M MgSO 4中为225 F / g和在1 M KOH中为184 F / g,高于先前报道的几微米厚的值。分层MXene电极。这项工作表明V 2 C MXene有望用于使用水性电解质进行能量存储。

更新日期:2018-10-16
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