2-Azaallyl Anions, 2-Azaallyl Cations, 2-Azaallyl Radicals, and Azomethine Ylides,Chemical Reviews

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2-Azaallyl Anions, 2-Azaallyl Cations, 2-Azaallyl Radicals, and Azomethine Ylides
Chemical Reviews ( IF 51.4 ) Pub Date : 2018-10-10 00:00:00 , DOI: 10.1021/acs.chemrev.8b00349
Shaojian Tang ₁ , Xia Zhang ₁ , Jiayue Sun ₁ , Dawen Niu ₁ , Jason J. Chruma ₁

Affiliation

This review covers the use of 2-azaallyl anions, 2-azaallyl cations, and 2-azaallyl radicals in organic synthesis up through June 2018. Particular attention is paid to both foundational studies and recent advances over the past decade involving semistabilized and nonstabilized 2-azaallyl anions as key intermediates in various carbon–carbon and carbon–heteroatom bond-forming processes. Both transition-metal-catalyzed and transition-metal-free transformations are covered. Azomethine ylides, which have received significant attention elsewhere, are discussed briefly with the primary focus on critical comparisons with 2-azaallyl anions in regard to generation and use.

中文翻译：

2-氮杂烯丙基阴离子，2-氮杂烯丙基阳离子，2-氮杂烯丙基自由基和氮杂甲叉基内酯

这篇综述涵盖了直至2018年6月在有机合成中使用2-氮杂烯丙基阴离子，2-氮杂烯丙基阳离子和2-氮杂烯丙基自由基。在过去的十年中，基础研究和最近的进展都得到了特别的关注，其中涉及半稳定和不稳定的2-氮杂烯丙基阴离子是各种碳-碳和碳-杂原子键形成过程中的关键中间体。涵盖了过渡金属催化的转化和无过渡金属的转化。简要介绍了在其他地方受到关注的苯甲亚胺基化物，其主要重点是与2-氮杂烯丙基阴离子在生成和使用方面的关键比较。

更新日期：2018-10-10

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