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Connections Between Theory and Experiment for Gold and Silver Nanoclusters
Annual Review of Physical Chemistry ( IF 11.7 ) Pub Date : 2018-04-20 00:00:00 , DOI: 10.1146/annurev-physchem-052516-050932
K.L. Dimuthu M. Weerawardene 1 , Hannu Häkkinen 2 , Christine M. Aikens 1
Affiliation  

Ligand-stabilized gold and silver nanoparticles are of tremendous current interest in sensing, catalysis, and energy applications. Experimental and theoretical studies have closely interacted to elucidate properties such as the geometric and electronic structures of these fascinating systems. In this review, the interplay between theory and experiment is described; areas such as optical absorption and doping, where the theory–experiment connections are well established, are discussed in detail; and the current status of these connections in newer fields of study, such as luminescence, transient absorption, and the effects of solvent and the surrounding environment, are highlighted. Close communication between theory and experiment has been extremely valuable for developing an understanding of these nanocluster systems in the past decade and will undoubtedly continue to play a major role in future years.

中文翻译:


金和银纳米簇的理论与实验之间的联系

配体稳定的金和银纳米颗粒在传感,催化和能量应用中具有巨大的当前兴趣。实验和理论研究紧密地相互作用以阐明诸如这些引人入胜的系统的几何和电子结构之类的特性。在这篇综述中,描述了理论与实验之间的相互作用。详细讨论了理论与实验之间建立良好联系的领域,例如光吸收和掺杂。并重点介绍了这些连接在最新研究领域中的现状,例如发光,瞬态吸收以及溶剂和周围环境的影响。

更新日期:2018-04-20
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