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Reduced polyaniline decorated reduced graphene oxide/polyimide nanocomposite films with enhanced dielectric properties and thermostability
Composites Part A: Applied Science and Manufacturing ( IF 8.1 ) Pub Date : 2018-04-02 , DOI: 10.1016/j.compositesa.2018.03.035
Hao Feng , Xinliang Fang , Xiaoyun Liu , Qibing Pei , Zhong-Kai Cui , Shifeng Deng , Jinlou Gu , Qixin Zhuang

This study reports the synthesis and characterization of reduced polyaniline decorated reduced graphene oxide/polyimide ([email protected]/PI) nanocomposite films with enhanced dielectric properties and thermostability. The steric effects of R-PANI decorated on the surface of RGO not only prevented the aggregation of RGO but also improved the dispersion of [email protected] nanosheets in the PI matrix, leading to higher dielectric constant (ε) and lower dielectric loss (tanδ) of the [email protected]/PI nanocomposite films than those of the RGO/PI nanocomposite films. The highest dielectric constant (25.84) was observed in the 20 wt% [email protected]/PI nanocomposite film (the mass fractions of RGO was 3.44%) with a low dielectric loss of 0.11 at 1 kHz. Furthermore, the 5 wt% weight loss temperature of the 20 wt% [email protected]/PI nanocomposite films was 480 °C, indicating the nanocomposite films are good candidates for dielectric materials under extreme temperature.



中文翻译:

还原的聚苯胺修饰的还原的氧化石墨烯/聚酰亚胺纳米复合膜,具有增强的介电性能和热稳定性

这项研究报告了还原的聚苯胺修饰的还原的氧化石墨烯/聚酰亚胺([电子邮件保护] / PI)纳米复合薄膜的合成和表征,该薄膜具有增强的介电性能和热稳定性。R-PANI在RGO表面装饰的空间效应不仅阻止RGO聚集,而且还改善了[受电子邮件保护的]纳米片在PI基质中的分散性,从而导致更高的介电常数(ε)和更低的介电损耗(tanδ) )(比受电子邮件保护的)/ PI纳米复合材料膜高)。在20 wt%[受电子邮件保护] / PI纳米复合膜(RGO的质量分数为3.44%)中观察到最高介电常数(25.84),在1 kHz时介电损耗低至0.11。此外,

更新日期:2018-04-02
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