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Potassium Fluoride‐Catalyzed Hydroboration of Aldehydes and Ketones: Facile Reduction to Primary and Secondary Alcohols
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-01-23 , DOI: 10.1002/ejoc.201901514 Krzysztof Kuciński 1 , Grzegorz Hreczycho 1, 2
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-01-23 , DOI: 10.1002/ejoc.201901514 Krzysztof Kuciński 1 , Grzegorz Hreczycho 1, 2
Affiliation
Fluoride ion – not only for silicon: the first example of a catalytic hydroboration strategy that uses an easily available inorganic salt, containing fluoride ion – potassium fluoride (KF), under very mild reaction conditions (air atmosphere, room temoerature) is described.
中文翻译:
氟化钾催化的醛和酮加氢硼化:易还原为伯醇和仲醇
氟离子-不仅用于硅:描述了催化硼氢化反应策略的第一个示例,该方法在非常温和的反应条件下(空气气氛,室温下)使用易于获得的无机盐,其中包含的氟离子-氟化钾(KF)。
更新日期:2020-01-23
中文翻译:
氟化钾催化的醛和酮加氢硼化:易还原为伯醇和仲醇
氟离子-不仅用于硅:描述了催化硼氢化反应策略的第一个示例,该方法在非常温和的反应条件下(空气气氛,室温下)使用易于获得的无机盐,其中包含的氟离子-氟化钾(KF)。