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Solvophobicity and Amphiphilic Self-Assembly in Neoteric and Nanostructured Solvents
Current Opinion in Colloid & Interface Science ( IF 7.9 ) Pub Date : 2020-01-01 , DOI: 10.1016/j.cocis.2019.12.009
Gregory G. Warr , Rob Atkin

The emergence of ionic liquids and deep eutectics as neoteric solvents that support surfactant self-assembly creates a vast new playing field for creating new forms of soft matter with distinctive properties. Solvophobic self-assembly in ionic liquids and deep eutectics has unique and novel features arising from strong interactions between constituents, high ionic strengths, and the molecular structures of the components, which can induce amphiphilic nanostructure in these non-aqueous solvents. This nanostructure is often reminiscent of microemulsions and sponge phases. Here we review recent new understanding of solvent nanostructure and its effect on self-assembly of surfactants and lipids.



中文翻译:

新型和纳米结构溶剂中的疏溶剂性和两亲性自组装

离子液体和深层共晶作为支持表面活性剂自组装的新型溶剂的出现,为创造具有独特性质的新型软物质创造了广阔的新领域。离子液体中的疏溶剂性自组装和深层共晶具有独特而新颖的特征,这是由于组分之间的强相互作用,高离子强度以及组分的分子结构所致,从而可以在这些非水溶剂中诱导出两亲性的纳米结构。这种纳米结构通常让人联想到微乳液和海绵相。在这里,我们回顾了对溶剂纳米结构及其对表面活性剂和脂质自组装的影响的最新新认识。

更新日期:2020-01-01
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