A series of whitlockite-type AgCa₁₀(PO₄)₇:RE³⁺ (RE = Sm, Dy) phosphors were successfully prepared via a high-temperature solid-state reaction method. The phase purity, photoluminescent properties, and thermal stability have been discussed in detail. Under 404 nm excitation, AgCa₁₀(PO₄)₇:Sm³⁺ exhibits red emission (604 nm) corresponding to the ⁴G_5/2 → ⁶H_7/2 transition. Under 352 nm excitation, AgCa₁₀(PO₄)₇:Dy³⁺ exhibits two emission peaks at 480 and 574 nm correspond to the ⁴F_9/2 → ⁶H_15/2 and ⁴F_9/2 → ⁶H_13/2 transition, respectively. The optimal AgCa₁₀(PO₄)₇:Sm³⁺ and AgCa₁₀(PO₄)₇:Dy³⁺ phosphors show good thermal stability. When the heating temperature reached 423 K, the relative intensity remains 90% and 86% compared to the luminescence intensity at room temperature of 298 K, respectively. Therefore, the above results indicate AgCa₁₀(PO₄)₇:RE³⁺ (RE = Sm, Dy) phosphors have potential applications in LEDs and display devices.

通过高温固相反应法成功地制备了一系列辉锰矿型AgCa ₁₀（PO ₄）₇：RE ³⁺（RE = Sm，Dy）荧光粉。已经详细讨论了相纯度，光致发光性质和热稳定性。在404 nm激发下，AgCa ₁₀（PO ₄）₇：Sm ³⁺表现出与⁴ G _5/2  →  ⁶ H _7/2跃迁相对应的红色发射（604 nm）。在352 nm激发下，AgCa ₁₀（PO ₄）₇：Dy ³⁺呈现在480 2个发射峰和574nm的对应于⁴ ˚F _9/2  →  ⁶ ħ _15/2和⁴ ˚F _9/2  →  ⁶ ħ _13/2分别过渡。最佳的AgCa ₁₀（PO ₄）₇：Sm ³⁺和AgCa ₁₀（PO ₄）₇：Dy ³⁺荧光粉显示出良好的热稳定性。当加热温度达到423 K时，相对强度分别比室温下298 K的发光强度高90％和86％。因此，以上结果表明AgCa₁₀（PO ₄）₇：RE ³⁺（RE = Sm，Dy）磷光体在LED和显示设备中具有潜在的应用。