当前位置: X-MOL 学术J. Solid State Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Crystal structure, spectroscopic, optical, thermal and magnetic studies of new orthoborate Sr2Co(BO3)2
Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2019-12-31 , DOI: 10.1016/j.jssc.2019.121167
F.-E. N’faoui , J. Aride , A. Boukhari , M. Taibi , H. Saadaoui , M. Rouziéres , M. Saadi , L. El Ammari

Single crystals of a novel distrontium cobalt diborate, Sr2Co(BO3)2, were successfully obtained from the melt at 1200 °C of the polycrystalline material. The powder of Sr2Co(BO3)2 compound was synthesized using standard solid state reaction at 850 °C. The refinement of the structure shows that Sr2Co(BO3)2 crystallizes in the monoclinic cell with the space group C2/m. The crystal structure is built from [CoO6] octahedra linked to [BO3] triangles by the vertices and to the SrO9 polyhedra by sharing two faces. The infrared analysis confirms the existence of BO3 vibrations group's. The calculated gap energy is Egap = 3.5eV for indirect gap model and Egap = 3.75eV for direct gap one. The magnetic measurements show that antiferromagnetic interactions are predominant in the studied borate. The high temperature X-ray diffraction and the differential scanning calorimetry allow to observe two anomalies in the temperature range of 400–800 °C which correspond to the phase transitions of Sr2Co(BO3)2.



中文翻译:

新原硼酸盐Sr 2 Co(BO 32的晶体结构,光谱,光学,热学和磁学研究

从多晶材料在1200°C的熔体中成功获得了新型二硼酸钴硼酸锶Sr 2 Co(BO 32的单晶。使用标准固态反应在850°C合成Sr 2 Co(BO 32化合物的粉末。结构的改进表明,Sr 2 Co(BO 32在空间群为C2 / m的单斜晶胞中结晶。晶体结构是由[CoO 6 ]八面体通过顶点与[BO 3 ]三角形和SrO 9连接而成的多面体通过共享两个面孔。红外分析证实了BO 3振动群的存在。 对于间接间隙模型,计算出的间隙能量为E gap = 3.5eV,而 对于直接间隙1则为E gap = 3.75eV。磁测量表明,在研究的硼酸盐中反铁磁相互作用占主导。高温X射线衍射和差示扫描量热法允许观察到温度在400-800°C范围内的两个异常,这对应于Sr 2 Co(BO 32的相变。

更新日期:2019-12-31
down
wechat
bug