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Electrochemical Selenation of Phosphonates and Phosphine Oxides
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2019-12-30 , DOI: 10.1016/j.tetlet.2019.151566
Shengmei Guo , Sen Li , Zhebin Zhang , Wenjie Yan , Hu Cai

An environmentally friendly electrocatalytic strategy for the synthesis of organoselenophospho-rus between phosphonates /phosphine oxides and selenols/diselenides is reported. The reaction was performed with metal-, base- and oxidant-free at room temperature, and affords the selenophosphorus products in good to excellent yields. The good tolerance of substituents enables the reaction more attractive in the preparation of organoselenophosphorus compounds.



中文翻译:

膦酸酯和氧化膦的电化学硒化

报道了在膦酸酯/膦氧化物和硒醇/二硒化物之间合成有机硒代磷酸环的环境友好的电催化策略。该反应是在室温下在无金属,无碱和无氧化剂的条件下进行的,并以良好或优异的收率提供了硒磷产物。取代基的良好耐受性使反应在制备有机硒磷化合物中更具吸引力。

更新日期:2019-12-30
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