Synthesis of an Air-Stable Pd(0) Catalyst Bearing Donor and Acceptor Phosphine Ligands,Organometallics

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Synthesis of an Air-Stable Pd(0) Catalyst Bearing Donor and Acceptor Phosphine Ligands
Organometallics ( IF 2.5 ) Pub Date : 2019-12-30 , DOI: 10.1021/acs.organomet.9b00646
Ryota Sato ₁ , Takaki Kanbara ₁ , Junpei Kuwabara ₁

Affiliation

We synthesized a new Pd(0) complex bearing π-acceptor ligands and a σ-donor ligand and confirmed that it exhibits high air stability and catalytic activity in direct arylation reactions. Moreover, stoichiometric reactions of the complex revealed that the σ-donor ligand does not dissociate from the Pd center.

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