Hydrothermal, gel oxalate precipitation and non-thermal glow discharge plasma synthesis methods are used for preparation of CuO/ZnO/Al₂O₃ mixed oxide catalysts. The XRD analysis reveals that the lowest relative crystallinity and crystallite size of different crystallite facets are obtained for CZA-OG-P sample which has been synthesized via hybrid glow discharge plasma-oxalate-precipitation method. The FESEM and TEM analyzes prove that CZA-OG-P nanocatalyst possesses the tiniest particles size, the lowermost aggregation of particles, the most homogenous distribution of particles among all three synthesized samples. Assessment of different samples in steam reforming of methanol shows that CZA-OG-P has the highest methanol conversion and the lowest carbon monoxide production. Also, with the evaluation of the performance of CZA-OG-P sample for long duration use, it is determined that the value of methanol conversion and selectivity of this sample are almost stable. Eventually, deactivation study of the CZA-OG-P used sample is studied through TG/DTG and SEM-EDX analysis.

采用水热法，草酸凝胶沉淀法和非热辉光放电等离子体合成法制备CuO / ZnO / Al ₂ O _3。混合氧化物催化剂。XRD分析表明，通过杂化辉光放电等离子体草酸盐沉淀法合成的CZA-OG-P样品获得了最低的相对结晶度和不同微晶面的微晶尺寸。FESEM和TEM分析证明，CZA-OG-P纳米催化剂在所有三个合成样品中均具有最小的粒径，最低的聚集度，最均匀的分布。对甲醇蒸汽重整中不同样品的评估表明，CZA-OG-P具有最高的甲醇转化率和最低的一氧化碳产量。另外，通过长期使用CZA-OG-P样品的性能评估，可以确定该样品的甲醇转化率和选择性几乎是稳定的。最终，