Chiral Bifunctional Selenide Catalysts for Asymmetric Bromolactonization,Asian Journal of Organic Chemistry

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Chiral Bifunctional Selenide Catalysts for Asymmetric Bromolactonization
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-01-30 , DOI: 10.1002/ajoc.201900688
Ryuichi Nishiyori ₁ , John R. J. Maynard _{1,

2} , Seiji Shirakawa ₁

Affiliation

The development of chiral selenium catalysts for asymmetric transformations has become a pre‐eminent topic in the field of organocatalytic chemistry. Herein, we report the development of chiral bifunctional selenide catalysts bearing a hydroxy group and discuss their application to asymmetric bromolactonization reactions. The importance of the bifunctional design of chiral selenide catalysts for enantioselective bromolactonizations was clearly demonstrated in the present work.

中文翻译：

手性双官能硒化物催化不对称溴化反应

用于不对称转化的手性硒催化剂的开发已成为有机催化化学领域的一个重要课题。在本文中，我们报道了带有羟基的手性双官能硒化物催化剂的发展，并讨论了它们在不对称溴内酯化反应中的应用。手性硒化物催化剂的双功能设计对于对映选择性溴内酯化的重要性已在本工作中得到了明确证明。

更新日期：2020-01-31

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