General User Guide for Partitioning of Tetraalkylammonium and Tetraalkylphosphonium Salts: Impacts of Cation, Anion, and Solvent,Organic Process Research & Development

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General User Guide for Partitioning of Tetraalkylammonium and Tetraalkylphosphonium Salts: Impacts of Cation, Anion, and Solvent
Organic Process Research & Development ( IF 3.1 ) Pub Date : 2020-01-10 , DOI: 10.1021/acs.oprd.9b00496
Richard J. Fox ₁ , Jun Qiu ₁

Affiliation

Using a gravimetric approach, the partitioning of 57 tetraalkylammonium and 10 tetraalkylphosphonium salts in 12 different organic solvent/water mixtures was determined. The data show that the partitioning is dramatically affected by the identity of the cation, anion, and solvent, and this comprehensive compilation can serve as a general user guide to aid as a starting point for reagent selection, especially in cases where efficient removal of the tetraalkylammonium or phosphonium salt is required.

中文翻译：

四烷基铵盐和四烷基phosph盐分配的通用用户指南：阳离子，阴离子和溶剂的影响

使用重量分析法，确定了57种四烷基铵盐和10种四烷基phosph盐在12种不同的有机溶剂/水混合物中的分配。数据表明，该分配受到阳离子，阴离子和溶剂特性的显着影响，该综合汇编可以用作一般用户指南，以帮助您选择试剂，尤其是在有效去除溶剂的情况下。需要四烷基铵或phospho盐。

更新日期：2020-01-10

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