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Facile synthesis of diarylsulfones from arenes and 3CdSO4·xH2O via mechanochemistry
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2019-12-26 , DOI: 10.1016/j.tetlet.2019.151567 Shuai Qin , Pu Zhang , Yu-Jun Qin , Zhi-Xin Guo
中文翻译:
借助机械化学方法从芳烃和3CdSO 4 ·xH 2 O轻松合成二芳基砜
更新日期:2019-12-27
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2019-12-26 , DOI: 10.1016/j.tetlet.2019.151567 Shuai Qin , Pu Zhang , Yu-Jun Qin , Zhi-Xin Guo
A variety of substituted diarylsulfones could be synthesized by simple arenes and 3CdSO4·xH2O in the presence of P2O5 under high-speed ball milling. It was suggest the aromatic sulfonation was performed by arene and in situ generated H2SO4, following-up by electrophilic substitution with another arene to give diarylsulfone.
中文翻译:
借助机械化学方法从芳烃和3CdSO 4 ·xH 2 O轻松合成二芳基砜
在高速球磨条件下,在P 2 O 5存在下,通过简单的芳烃和3CdSO 4 ·xH 2 O可以合成多种取代的二芳基砜。这表明芳族磺化反应是由芳烃进行的,并原位生成H 2 SO 4,随后通过亲电取代另一种芳烃得到二芳基砜。