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Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines.
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2020-01-13 , DOI: 10.1039/c9ob02457c
Jiao Gui 1 , Haisheng Xie 1 , Fengjuan Chen 1 , Zhipeng Liu 1 , Xiaoqi Zhang 2 , Fubin Jiang 3 , Wei Zeng 1
Affiliation  

A Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines in the presence of TPT and CF3CO2H has been developed. This transformation provides a green approach to alpha-amino-substituted arylalkanes under metal-free conditions.

中文翻译:

布朗斯台德酸/可见光促进的乙烯基芳烃与芳基胺的马氏化学加氢胺化。

在TPT和CF3CO2H存在下,开发了由芳基胺与芳基胺进行的布朗斯台德酸/可见光促进的乙烯基芳烃的马尔科夫尼科夫加氢胺化反应。这种转变为在无金属条件下制备α-氨基取代的芳基烷烃提供了一种绿色方法。
更新日期:2020-02-13
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