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There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(iii) single-ion magnet.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-01-10 , DOI: 10.1039/c9cc07292f Angelos B Canaj 1 , Sourav Dey , Oscar Céspedes , Claire Wilson , Gopalan Rajaraman , Mark Murrie
Chemical Communications ( IF 4.3 ) Pub Date : 2020-01-10 , DOI: 10.1039/c9cc07292f Angelos B Canaj 1 , Sourav Dey , Oscar Céspedes , Claire Wilson , Gopalan Rajaraman , Mark Murrie
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A new air-stable sulfur-ligated Dy(iii) single-ion magnet has been successfully isolated with Ueff = 638 K and hysteresis loops open up to 7 K. In silico studies show that the S co-ligands significantly boost the axiality and that Te- and Se-donors have the potential to further enhance the magnetic properties.
中文翻译：
柔软无可厚非：使用硫配体增加Dy（iii）单离子磁体的轴向性。
已成功分离出一种新型的空气稳定的硫连接的Dy（iii）单离子磁体，其Ueff = 638 K，并且磁滞回线可打开至7K。计算机研究表明，S共配体可显着提高轴向性，并且Te和Se供体具有进一步增强磁性的潜力。
更新日期：2020-01-10
中文翻译：
柔软无可厚非：使用硫配体增加Dy（iii）单离子磁体的轴向性。
已成功分离出一种新型的空气稳定的硫连接的Dy（iii）单离子磁体，其Ueff = 638 K，并且磁滞回线可打开至7K。计算机研究表明，S共配体可显着提高轴向性，并且Te和Se供体具有进一步增强磁性的潜力。
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