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Pd-Ru nanocatalysts derived from a Pd-induced aerogel for dramatic boosting of hydrogen release.
Nanoscale ( IF 5.8 ) Pub Date : 2020-01-09 , DOI: 10.1039/c9nr09307a Xiaojiao Yang 1 , Jianyu Wei 2 , Qi Wang 3 , Maobing Shuai 1 , Guozong Yue 1 , Peilong Li 1 , Deshun Huang 1 , Didier Astruc 3 , Pengxiang Zhao 1
Nanoscale ( IF 5.8 ) Pub Date : 2020-01-09 , DOI: 10.1039/c9nr09307a Xiaojiao Yang 1 , Jianyu Wei 2 , Qi Wang 3 , Maobing Shuai 1 , Guozong Yue 1 , Peilong Li 1 , Deshun Huang 1 , Didier Astruc 3 , Pengxiang Zhao 1
Affiliation
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Alloyed bimetallic Pd-Ru nanocatalysts prepared by in situ reduction of a mixture of a Ru(iii) source and a Pd(ii)@alkyne-PVA aerogel and characterized by TEM and XPS exhibit very highly catalytic activity towards hydrogen release from ammonia borane hydrolysis with a TOF value of 578.2 molH2 molcat-1 min-1.
中文翻译：
Pd-Ru纳米催化剂衍生自Pd诱导的气凝胶，可显着促进氢释放。
通过原位还原Ru（iii）源和Pd（ii）@炔烃-PVA气凝胶的混合物制备的合金化双金属Pd-Ru纳米催化剂，并用TEM和XPS表征，对氨硼烷水解中的氢释放具有很高的催化活性。 TOF值为578.2 molH2 molcat-1 min-1。
更新日期：2020-01-09
中文翻译：
Pd-Ru纳米催化剂衍生自Pd诱导的气凝胶，可显着促进氢释放。
通过原位还原Ru（iii）源和Pd（ii）@炔烃-PVA气凝胶的混合物制备的合金化双金属Pd-Ru纳米催化剂，并用TEM和XPS表征，对氨硼烷水解中的氢释放具有很高的催化活性。 TOF值为578.2 molH2 molcat-1 min-1。
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