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Combustion synthesis of battery-type positive electrodes for robust aqueous hybrid supercapacitor
Journal of Energy Storage ( IF 9.4 ) Pub Date : 2019-12-23 , DOI: 10.1016/j.est.2019.101160
A. Bello , D.M. Sanni , S.A. Adeniji , V. Anye , K. Orisekeh , M. Kigozi , R. Koech

Producing materials with suitable features including robust, and high electrical conductivity for the realization of excellent electrochemical performance for supercapacitor devices remains a great challenge. In this regard, we optimize and used the combustion synthesis technique assisted with urea for the production of a positive electrode based on battery type lithium manganese oxide (LiMnO) and activated carbon as negative electrode materials for high voltage hybrid devices in aqueous electrolytes. The samples were analyzed with X-ray diffraction, Raman spectroscopy, and scanning electron microscopy. The structural properties of the material were studied and hybrid devices fabricated present a specific capacitance of 65 F g−1 and 78 F g−1, at 0.5 A g−1 in 1 M Li2SO4 and 1 M Na2SO4 respectively, with long-term stability after continuous cycling. These result shows that this strategy can revolutionize new ways to the synthesis of a plethora of materials for high voltage energy storage applications.



中文翻译:

鲁棒水性混合超级电容器电池型正极的燃烧合成

为了实现超级电容器器件的优异电化学性能,生产具有合适特性(包括坚固且高电导率)的材料仍然是一个巨大的挑战。在这方面,我们优化并使用了尿素辅助的燃烧合成技术,用于生产基于电池型锂锰氧化物(LiMnO)和活性炭的正极,作为水性电解质中高压混合装置的负极材料。用X射线衍射,拉曼光谱和扫描电子显微镜分析样品。所研究的材料的结构性质和混合设备制造的65 F G存在的特定电容-1和78 F G -1 0.5,A克-1在1 M Li 2 SO 4和1 M Na 2 SO 4中分别具有连续循环后的长期稳定性。这些结果表明,该策略可以革新用于高压储能应用的多种材料合成的新方法。

更新日期:2019-12-23
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