Intramolecular Metal-Free N-N Bond Formation with Heteroaromatic Amines: Mild Access to Fused-Triazapentalene Derivatives.,Chemistry - A European Journal

当前位置： X-MOL 学术 › Chem. Eur. J. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Intramolecular Metal-Free N-N Bond Formation with Heteroaromatic Amines: Mild Access to Fused-Triazapentalene Derivatives.
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2019-12-24 , DOI: 10.1002/chem.201905558
Matthieu Daniel _{1,

2} , Marie-Aude Hiebel ₁ , Gérald Guillaumet ₁ , Eric Pasquinet ₂ , Franck Suzenet ₁

Affiliation

Formation of N-N bonds may offer an original approach to various nitrogen-containing heterocycles with numerous applications. For this purpose, we found that readily available heteroaromatic amines are appropriate substrates for providing an efficient and innovative approach for the formation of N-N bonds in the presence of iodine (III) reagent in very mild conditions. This method makes it possible to synthesize nitrogen rich triazapentalene derivatives exhibiting fluorescent properties, inaccessible with existing approaches.

中文翻译：

杂芳族胺形成无分子内金属的NN键：轻松获得熔融三苯并戊烯衍生物。

NN键的形成可能为具有多种应用的各种含氮杂环化合物提供原始方法。为此，我们发现，容易获得的杂芳族胺是合适的底物，可为在非常温和的条件下在存在碘（III）试剂的情况下提供有效且创新的方法来形成NN键。该方法使合成具有荧光性质的富氮三氮杂戊烯衍生物成为可能，这是现有方法无法达到的。

更新日期：2020-01-23

点击分享查看原文

点击收藏

阅读更多本刊最新论文