The Right Light: De Novo Design of a Robust Modular Photochemical Reactor for Optimum Batch and Flow Chemistry,ChemPhotoChem

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The Right Light: De Novo Design of a Robust Modular Photochemical Reactor for Optimum Batch and Flow Chemistry
ChemPhotoChem ( IF 3.0 ) Pub Date : 2019-09-25 , DOI: 10.1002/cptc.201900203
Holly E. Bonfield ₁ , Kayleigh Mercer ₁ , Alba Diaz‐Rodriguez ₁ , Gemma C. Cook ₁ , Blandine S. J. McKay ₁ , Pawel Slade ₁ , George M. Taylor ₁ , Wei Xiang Ooi ₁ , Jason D. Williams ₁ , Jack P. M. Roberts _{1,

2} , John A. Murphy ₂ , Luca Schmermund ₃ , Wolfgang Kroutil ₃ , Tamara Mielke ₄ , Jared Cartwright ₄ , Gideon Grogan ₄ , Lee J. Edwards ₁

Affiliation

Having identified inconsistencies when repeating literature examples of photochemical transformations and difficulties recreating experimental setups, we devised several criteria that an ideal lab‐scale reactor should achieve. Herein, we introduce a versatile photoreactor for high‐throughput screening, preparative‐scale batch reactions and continuous processing, all with a single light source. The reactor utilizes interchangeable arrays of pseudo‐monochromatic high‐power LEDs in a range of synthetically useful wavelengths, combined with excellent temperature control. Moreover, light intensity can be modulated in an accurate and straightforward manner. This system has subsequently been tested on a range of literature methodologies.

中文翻译：

合适的光源：用于最佳批料和流动化学的鲁棒模块化光化学反应器的从头设计

在重复有关光化学转化的文献示例和重新建立实验装置的困难时发现不一致的地方之后，我们设计了理想实验室规模反应器应达到的几个标准。本文中，我们介绍了一种多功能光反应器，可通过单个光源进行高通量筛选，制备规模的批反应和连续处理。该反应堆利用了可替换的伪单色高功率LED阵列，这些阵列具有各种合成有用的波长，并具有出色的温度控制能力。此外，可以以准确和直接的方式调制光强度。随后对该系统进行了一系列文献方法论的测试。

更新日期：2019-09-25

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