Abstract The promotion effect of TBAC on the dissociation condition of the studied system is determined under the present experimental data. A combination of the van der Waals–Platteeuw solid solution theory, binding mean spherical approximation electrolyte model and modified Peng–Robinson equation of state is used for calculation of the hydrate, aqueous solution and gaseous phases properties, respectively. The results are also compared with the experimental data for other salts such as tetra-n-butyl-ammonium bromide (TBAB) and tetra-hydro furan (THF). A good agreement between the model predictions and experimental data is found with an absolute average relative deviation of 13.1%.

中文翻译：

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存在四正丁基氯化铵 (TBAC) 时二氧化碳的半包合物水合物相平衡：实验测量和热力学建模

摘要 根据目前的实验数据，确定了TBAC 对所研究体系解离条件的促进作用。van der Waals-Platteeuw 固溶体理论、结合平均球面近似电解质模型和修正的 Peng-Robinson 状态方程的组合分别用于计算水合物、水溶液和气相的性质。还将结果与其他盐的实验数据进行比较，例如四正丁基溴化铵 (TBAB) 和四氢呋喃 (THF)。发现模型预测和实验数据之间具有良好的一致性，绝对平均相对偏差为 13.1%。