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Biosynthetic Pathways to Nonproteinogenic α-Amino Acids.
Chemical Reviews ( IF 52.758 ) Pub Date : 2019-12-23 , DOI: 10.1021/acs.chemrev.9b00408
Jason B Hedges,Katherine S Ryan

Natural nonproteinogenic amino acids vastly outnumber the well-known 22 proteinogenic amino acids. Such amino acids are generated in specialized metabolic pathways. In these pathways, diverse biosynthetic transformations, ranging from isomerizations to the stereospecific functionalization of C-H bonds, are employed to generate structural diversity. The resulting nonproteinogenic amino acids can be integrated into more complex natural products. Here we review recently discovered biosynthetic routes to freestanding nonproteinogenic α-amino acids, with an emphasis on work reported between 2013 and mid-2019.
更新日期:2019-12-23

 

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