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Selective removal of organic and inorganic air pollutants by adjusting the g-C3N4/TiO2 ratio
Catalysis Today ( IF 5.2 ) Pub Date : 2019-12-20 , DOI: 10.1016/j.cattod.2019.12.021
Ilias Papailias , Nadia Todorova , Tatiana Giannakopoulou , Dana Dvoranová , Vlasta Brezová , Dimitra Dimotikali , Christos Trapalis

During the recent years, g-C3N4/TiO2 composites have been regarded as efficient photocatalysts for the removal of air pollutants. The combination of these materials gives excellent photocatalytic performances, as each ones advantage covers the disadvantages of the other. In the present study, g-C3N4/TiO2 heterostructures were synthesized by mixing chemically exfoliated g-C3N4 with commercial TiO2 P25 in different ratios and were examined for the removal of NOx and acetaldehyde under visible-light irradiation. The results of photocatalytic tests in correlation with the EPR experiments revealed that heterostructures containing higher amount of TiO2 are efficient in systems where the attack of hydroxyl radicals prevails (acetaldehyde), while dominant g-C3N4 content provides effectiveness in systems where superoxide radical anions play the key role (NOx). This outcome is directly coupled with the energy positions of conduction- and valence-band edges of each material.



中文翻译:

通过调节gC 3 N 4 / TiO 2的比值选择性去除有机和无机空气污染物

近年来,gC 3 N 4 / TiO 2复合材料被认为是用于去除空气污染物的有效光催化剂。这些材料的组合可提供出色的光催化性能,因为每个优点都覆盖了另一个缺点。在本研究中,GC 3 Ñ 4 /二氧化钛2个异质结构通过混合化学剥离的GC合成3 Ñ 4与商业的TiO 2 P25以不同比例并检查用于去除NO的X和乙醛在可见光照射下。与EPR实验相关的光催化测试结果表明,含有较高含量TiO 2的异质结构在占主导地位的羟基自由基(乙醛)的体系中是有效的,而占主导地位的gC 3 N 4含量在超氧自由基阴离子的体系中具有有效性发挥关键作用(NO x)。该结果与每种材料的导带和价带边缘的能量位置直接相关。

更新日期:2019-12-20
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