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Inhibition of volatilization and polycrystalline cracking, and the optical properties of β-Ga2O3 grown by the EFG method
CrystEngComm ( IF 2.6 ) Pub Date : 2019/12/20 , DOI: 10.1039/c9ce01294j
Huili Tang 1, 2, 3, 4, 5 , Nuotian He 1, 2, 3, 4, 5 , Hao Zhang 1, 2, 3, 4, 5 , Bo Liu 1, 2, 3, 4, 5 , Zhichao Zhu 4, 5, 6, 7 , Mengxuan Xu 7, 8, 9, 10 , Liang Chen 7, 11, 12, 13 , Jinliang Liu 7, 11, 12, 13 , Xiaoping Ouyang 7, 11, 12, 13 , Jun Xu 1, 2, 3, 4, 5
Affiliation  

Large-size β-Ga2O3 single crystals without sub-grain boundaries and cracks were grown by the optimized EFG technology. The thermal volatilization of Ga2O3, polycrystalline growth and cracking were systematically characterized and analyzed from phenomenological and crystallographic points. The proportion of CO2 gas in the growth atmosphere and axial temperature gradient of the thermal field play important roles in suppressing the thermal decomposition and volatilization of a Ga2O3 melt. A higher seeding temperature could effectively inhibit polycrystalline growth. Furthermore, the effects of annealing in an oxygen environment on the optical properties of β-Ga2O3 crystals were discussed.

中文翻译:

抑制挥发和多晶裂纹,以及通过EFG方法生长的β-Ga2O3的光学性质

大尺寸的β-Ga 2 ö 3没有子晶界和裂纹单晶通过优化EFG技术中生长。从现象学和晶体学的角度对Ga 2 O 3的热挥发,多晶生长和裂纹进行了系统地表征和分析。生长气氛中CO 2气体的比例和热场的轴向温度梯度在抑制Ga 2 O 3的热分解和挥发中起重要作用。熔化。较高的晶种温度可以有效地抑制多晶生长。此外,退火的在氧气环境中的β-Ga的光学特性的影响2个ö 3进行了讨论晶体。
更新日期:2020-02-13
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