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Initiating Mechanism of the Anionic Polymerization of Methacrylates with t‐BuOK and the Synthesis of ABA Type Triblock Copolymers
Macromolecular Chemistry and Physics ( IF 2.5 ) Pub Date : 2019-12-20 , DOI: 10.1002/macp.201970051
Tongyuan Zhang , Anna Zheng , Guijin Zou , Dafu Wei , Xiang Xu , Yong Guan

Back Cover: In article number 1900390, Anna Zheng, Yong Guan, and co‐workers report that using t‐BuOK as initiator, an ABA‐type triblock copolymer (PMMA‐b‐PLMA‐b‐PMMA) is synthesized at 0 °C without using any sidereaction inhibitors and the monomer conversion is over 97%, which paves the way for the synthesis of thermoplastic elastomers with full polar monomers and full saturated chains by anionic polymerization.
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中文翻译:

t-BuOK引发甲基丙烯酸酯阴离子聚合反应机理及ABA型三嵌段共聚物的合成

封底:Anna Zheng,Yong Guan及其同事在编号1900390中报告说,使用t- BuOK作为引发剂,会在0°C时合成ABA型三嵌段共聚物(PMMA-b-PLMA-b-PMMA)无需使用任何副反应抑制剂,单体转化率超过97%,这为通过阴离子聚合合成具有全极性单体和全饱和链的热塑性弹性体铺平了道路。
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更新日期:2019-12-20
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