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Hydrocracking of hydrotreated Light Cycle Oil to mono aromatics over non-noble bi-functional (Ni-W supported) zeolite catalysts
Catalysis Today ( IF 5.2 ) Pub Date : 2019-12-19 , DOI: 10.1016/j.cattod.2019.12.027
M. Anilkumar , Ninad Loke , Vilas Patil , Rahul Panday , Sreenivasarao. G

The bi-functional catalysts comprising non-noble metals such as Ni-W supported on zeolites were prepared to study hydrocracking of hydrotreated Light Cycle Oil (LCO) conversion into mono-aromatics. The three Ni-W supported zeolite catalysts with mixture of Y and Beta (Catalyst-A), Y (Catalyst-B), and Beta zeolites (Catalyst-C) were prepared by wetness impregnation method and characterized by using different techniques to understand the physico-chemical properties. The characterization results indicated that Ni-W supported on Beta zeolite catalyst has higher overall acidity and strong interaction between the H2W12O40 and Ni2+ ions than Ni-W supported on mixture of Y & Beta, and Y zeolites. Furthermore, Beta zeolite catalyst exhibited tetrahedral tungstate species, which are due to strong interaction between support and metal ions. Among these catalysts, Ni-W supported on Beta zeolite catalyst showed high conversion for mono-aromatic 2 ring, and di-aromatics and selectivity towards mono-aromatics (43.5%). The high conversion of this catalyst could be due to higher total acidity and the presence of tetragonal tungsten species. High selectivity of mono-aromatics may be due to larger average pore diameter of the Beta zeolite.



中文翻译:

在非贵族双功能(Ni-W负载)沸石催化剂上将加氢处理的轻循环油加氢裂化为单芳烃

制备了包含非贵金属(例如负载在沸石上的Ni-W)的双功能催化剂,以研究加氢处理的轻循环油(LCO)转化为单芳烃的加氢裂化。通过湿法浸渍法制备了三种Y-B负载的Y-B,C和B的Ni-W负载型沸石催化剂,并采用不同的技术对其进行了表征,以了解理化特性。表征结果表明,负载在β沸石催化剂上的Ni-W具有较高的整体酸度,且H 2 W 12 O 40与Ni 2+之间具有较强的相互作用。Y和Beta以及Y沸石的混合物中负载的离子比Ni-W高。此外,由于载体和金属离子之间的强相互作用,β沸石催化剂显示出四面体钨酸盐物种。在这些催化剂中,负载在Beta沸石催化剂上的Ni-W对单芳族2环和二芳族化合物的转化率高,对单芳族化合物的选择性高(43.5%)。该催化剂的高转化率可能归因于较高的总酸度和四方钨物种的存在。单芳族化合物的高选择性可能是由于β沸石的平均孔径更大。

更新日期:2019-12-19
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