This article is a review of the current state of knowledge about the so-called charge-inverted hydrogen bond—the type of interaction proposed 10 years ago. Numerous examples of model dimers and molecules in which this type of interaction exists in the inter- and intramolecular forms, respectively, as well as systems actually existing and studied by experimental and theoretical methods will be presented. The results of extensive theoretical research on the physical nature of charge-inverted hydrogen bonds will be thoroughly discussed. Dimers with a recently described hydride-carbene bond, i.e., a particular case of charge-inverted hydrogen bond in which the carbene carbon atom plays the role of an atom with the electron lone-pair vacancy, will also be presented.

中文翻译：

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十年的电荷倒置氢键

本文回顾了有关所谓的电荷反转氢键（10 年前提出的相互作用类型）的当前知识状态。将介绍许多模型二聚体和分子的例子，其中这种相互作用分别以分子间和分子内形式存在，以及通过实验和理论方法实际存在和研究的系统。将彻底讨论关于电荷反转氢键物理性质的广泛理论研究的结果。还将介绍具有最近描述的氢化物-卡宾键的二聚体，即电荷反转氢键的一种特殊情况，其中卡宾碳原子扮演具有电子孤对空位的原子的角色。