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Nitrene Transfer Reactions for Asymmetric C–H Amination: Recent Development
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-01-17 , DOI: 10.1002/ejoc.201901562
Hiroki Hayashi 1 , Tatsuya Uchida 1, 2
Affiliation  

Transition‐metal‐catalyzed C–H bond amination through nitrene transfer is a straightforward method to provide chiral aminated compounds. This minireview focuses on recent strategies for the asymmetric C–H amination towards enantioenriched products with several nitrogen sources cataylzed by small molecule complexes or artificial metalloenzymes.
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中文翻译:

用于不对称C–H胺化的丁二烯转移反应:最新进展

通过腈转移的过渡金属催化的CH键胺化是提供手性胺化化合物的直接方法。本篇综述着重于对不对称C–H胺化反应的方法,该方法涉及对映体富集的产品,其中小分子配合物或人造金属酶催化了几种氮源。
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更新日期:2020-01-17
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