Ce-doped MIL-101-NH₂ sensitized Ag₃PO₄ composites were successfully prepared using an in-situ ion-exchange deposition method. The adsorption capacity of these composites was observed to decrease as Ce/Fe ratio was increased. Under white LED irradiation, the addition of Ce to MIL-101-NH₂ improved the visible light response of the metal organic framework (MOF). The obtained Ce-doped MIL-101-NH₂ sensitized Ag₃PO₄composite shows excellent photocatalytic activity and stability for the degradation of pollutants. This superior performance can be explained by the redox couple Ce³⁺/ Ce⁴⁺ accelerating the migration of photo-induced holes, thereby facilitating efficient separation of photo-generated electron–hole pairs.

使用原位离子交换沉积方法成功制备了Ce掺杂的MIL-101-NH ₂敏化的Ag ₃ PO ₄复合材料。观察到这些复合材料的吸附能力随着Ce / Fe比的增加而降低。在白光LED照射下，向MIL-101-NH _2中添加Ce可以改善金属有机骨架（MOF）的可见光响应。所获得的Ce掺杂的MIL-101-NH ₂敏化的Ag ₃ PO ₄复合材料表现出优异的光催化活性和对污染物降解的稳定性。氧化还原对Ce ³⁺ / Ce ⁴⁺可以解释这种优越的性能 加速了光致空穴的迁移，从而促进了光生电子-空穴对的有效分离。