Catalytic Carbonylation and Carboxylation of Organosulfur Compounds via C−S Cleavage,Chemistry - An Asian Journal

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Catalytic Carbonylation and Carboxylation of Organosulfur Compounds via C−S Cleavage
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2020-01-22 , DOI: 10.1002/asia.201901644
Keisuke Nogi ₁ , Hideki Yorimitsu ₁

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Transition‐metal‐catalyzed carbonylation with CO gas occupies a privileged position in organic synthesis for the synthesis of carbonyl compounds. Although this attractive and useful chemistry has led many researchers to investigate carbonylative transformations of various organic (pseudo)halides, C−S‐cleaving carbonylation of organosulfur compounds has been fairly limited. Recently, a broad spectrum of C−S‐cleaving transformations has been emerging in the field of cross‐coupling. In light of the importance of carbonyl compounds as well as considerable advancement for employing organosulfur compounds as competent surrogates of (pseudo)halides, carbonylative transformations of C−S bonds should be of high value. This Minireview focuses on catalytic C−S carbonylation of organosulfur compounds with CO or its equivalents. In addition, reductive carboxylation of C−S bonds with CO₂ is described.

中文翻译：

通过C-S裂解催化有机硫化合物的羰基化和羧化

用CO气体进行过渡金属催化的羰基化在羰基化合物合成的有机合成中占有特殊的位置。尽管这种吸引人且有用的化学方法使许多研究人员研究了各种有机（假）卤化物的羰基化转化，但是有机硫化合物的C-S裂解羰基化作用还是相当有限的。最近，在交叉耦合领域中出现了各种各样的C-S裂解转换。考虑到羰基化合物的重要性以及使用有机硫化合物作为（伪）卤化物的有效替代物的显着进展，CS键的羰基化转化应具有很高的价值。本微型评论的重点是有机硫化合物与CO或其等价物的催化C-S羰基化反应。此外，描述图₂。

更新日期：2020-01-23

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